General Scale in Current Drawing Preferences only refers to the size of dimension elements like text and arrows.
The printing scale is set in Print Preview.
You also should tell your printer in it's windows driver settings to print at 100%, otherwise it might scale the print down to within the printable area. This might be your problem.
Have a look into the manual
https://librecad.readthedocs.io/en/latest/index.htmlUse the development version 2.2.0 rc3. It is stable and improved in many respects.