Sadly, this is not possible in LibreCAD yet.
A spline has very complex math which is not implemented. So all kind of tools which need to find intersections or tangents with splines don't work.
Most applies to ellipses and elliptical arcs too, they also do not support all tools.
You have to use lines or arcs for the fillet tool. So you need an approximation of the spline build from circular arcs. Sadly LibreCAD has no tool for this too.
An option in LibreCAD is to save the drawing in R12 format. The older DXF R12 format has no SPLINE or ELLIPSE entities and thus these entities are converted to polylines when saved. But it's not an arc approximation, splines or ellipses are converted to a small, straight line segments in R12.
You can give it a try, when you save the drawing under a new name in DXF R12 and then reopen it.
For printing or as a stencil, this may be sufficient. But if you want to do any kind of machining, you should first try if the converted spline works fine.
Armin
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