well, are you sure that your two lines that overlaps with color blending actually lies on the same ray and have the same width?
I've made just a quick test (on 2.2.2-alpha version)- and overlapped lines are rendered as expected - the line on top covers the line below without colors blending.
The following image illustrates lines overlapping in my environment (red line is over yellow line):

Which version of LC do you use and under which operating system? Also, is antialiasing is enabled or disabled?